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Öğe A detailed study on the optical properties of 3-benzoyl-7-hydroxy coumarin compound in different solvents and concentrations(Macedonian Journal of Chemistry and Chemical Engineering, 2019) Kurt, Adnan; Gündüz, Bayram; Koca, MuratA coumarin-derived compound, 3-benzoyl-7-hydroxy coumarin (BHYC), is synthesized to determine its optoelectronic properties, including absorbance band edge, optical band gap, transmittance, refractive index, electrical susceptibility, volume-surface energy loss functions and optical/electrical conductance parameters. The absorbance spectra of BHYC in dimethylformamide (DMF) and dimethylsulfoxide ( DMSO) solvents exhibit maximum peaks at 350 and 353 nm, respectively, in the near-ultraviolet region. The absorbance band edge values of BHYC in DMF and DMSO are 2.526 and 2.500 eV, respectively. The optical band gap of BHYC varies from 2.560 to 2.408 eV with increasing molarity. In contrast, the refractive index of BHYC increases from 2.47 to 2.95 with changing molarity. The obtained results show that 3-benzoyl-7-hydroxy coumarin exhibits a semiconductor behavior and it may be an important candidate for many optoelectronic devices, such as diodes, photodiodes and sensors.Öğe A study on the optoelectronic parameters of 4-chloromethyl-7-hydroxy coumarin in various solvents and concentrations(Türkiye Kimya Derneği, 2021) Kurt, Adnan; Gündüz, Bayram; Koca, MuratA coumarin derivative, namely 4-chloromethyl-7-hydroxy coumarin (CMEHC), was synthesized in order to test the concentration and solvent effect on its optical properties. The spectral characterization of this compound was accomplished by FTIR and 1H-NMR techniques. The UV absorption spectra of CMEHC compound in various solvents (THF, DMSO, DMF) were recorded with a UV–VIS spectrophotometer. The optical parameters such as maximum peak position, absorption band edge, and direct allowed bandgap were reported for these solvents and also various concentrations. The lowest direct allowed bandgap was obtained with THF. The absorbance spectra of CMEHC compound were dominant at the near ultraviolet region. The refractive index values were compared with each other using Moss, Ravindra, Herve-Vandamme, Reddy and Kumar-Singh relations.