Benzimidazole-based N-heterocyclic carbene ruthenium(II) complexes: Synthesis and C-H bond activation properties

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dc.contributor.authorAkkoc, Mitat
dc.date.accessioned2026-06-19T06:39:46Z
dc.date.available2026-06-19T06:39:46Z
dc.date.issued2022
dc.departmentMalatya Turgut Özal Üniversitesi
dc.description.abstractThe transition-metal-promoted C-H activation has become an efficient as well as an atom-economic methodology for the synthesis of a wide array of organic molecules. Herein, the reaction of RuCl2(p-cymene)](2) with 1,3-dialkylbenzimidazolium salts ( 1a-c ) in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes ( 2a-c ). All synthesized compounds were characterized by elemental analysis and NMR spectroscopy. The catalytic activity of [Cl2Ru(eta(6)-arene, eta(1)-carbene)] complexes ( 2a-c ) were evaluated in the direct arylation of 2-phenylpyridine and 1-phenylpyrazole with (hetero)aryl chlorides derivative. (C) 2022 Published by Elsevier B.V.
dc.identifier.doi10.1016/j.molstruc.2022.133999
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.orcid0000-0001-8641-8958
dc.identifier.scopus2-s2.0-85136590761
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2022.133999
dc.identifier.urihttps://hdl.handle.net/20.500.12899/5787
dc.identifier.volume1270
dc.identifier.wosWOS:000860322900008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAkkoc, Mitat
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20260612
dc.subjectC-H Activation
dc.subjectDirect Arylation
dc.subject1-Phenyl Pyrazole
dc.subject2-Phenyl Pyridine
dc.subjectRu-Nhc
dc.titleBenzimidazole-based N-heterocyclic carbene ruthenium(II) complexes: Synthesis and C-H bond activation properties
dc.typeArticle

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