Hybrid portland cement-slag-based geopolymer mortar: Strength, microstructural and environmental assessment

Küçük Resim Yok

Tarih

2025

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The aim of the current work is to investigate the strength, microstructure, environmental and economic effects of hybrid ordinary portland cement (PC) and ground granulated blast-furnace slag (GGBS) based geopolymer mortar as an alternative to ordinary cement mortar. Eleven mixtures were prepared for this. In this regard, PC was blended with GGBS content of 0-90 wt% in these mixtures. The designed mortar samples were cured at ambient temperature (20 +/- 2 degrees C) to be more applicable in the construction industry, unlike most geopolymer productions and ordinary PC mortar samples were also produced to be comparable to the designed hybrid PC/ GGBS-based geopolymer mortars. The compressive strength (fc) development, ultrasonic pulse velocity (UPV), and dynamic modulus of elasticity (Edyn) values of these ten-hybrid PC/GGBS-based geopolymer mortars were compared with the designed ordinary PC mortar. The results indicated that the incorporation of 20 % PC with 80 % GGBS in the alkali-activated system had the best 28-day compressive strength value with 74.26 MPa, which was 91.07 % higher than that of the designed ordinary PC mortar. The techniques of scanning electron microscopy (SEM)-EDS, Fourier transform-infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA) were used to identify the microstructural changes caused by the use of ambient temperature cured hybrid 20 % cement-80 % GGBS based alkali-activated mortar. The relatively higher ratios of Ca/Al and Ca/Si compared to ordinary PC mortar proved the more excellent binding property of the C-A-S-H gel, and a denser microstructure was observed in the SEM results. The superior strength development of the hybrid 20 %cement-80 %GGBS alkaliactivated mortar was confirmed by the formation of highly cross-linked C-S-H and C-A-S-H gels due to the higher degree of polymerization and hydration. Additionally, the designed hybrid 20% cement-80 % GGBS geopolymer mortar presented significant environmental and economic benefits compared to those of ordinary PC mortar, with 32.6 % and 23.5 % lower CO2 emission and cost intensity values, respectively.

Açıklama

Anahtar Kelimeler

Cement, Granulated Blast-Furnace Slag, Hybrid Cement Geopolymer Composite, Strength And Microstructural Analysis, Environmental And Economic Impact

Kaynak

Process Safety and Environmental Protection

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

195

Sayı

Künye